In a bowl large enough to hold your 4 pork chops, combine the marinade ingredients: (olive oil, Balsamic vinegar, brown sugar, Dijon mustard, minced garlic, smoked paprika, salt, and pepper). Stir to combine, then place the pork chops into the bowl and marinade refrigerated for at least 30 minutes.
Heat a large skillet or frying pan, with the second portion of oil to medium high heat. Remove the pork chops from the marinade and place them in the pan to cook. Set aside the bowl of marinade to add later.
Cook the pork chops until they take on a brown coloring (they will already be slightly brown due to the marinade), about 3-4 minutes per side. After cooking both sides, add the marinade into the skillet or frying pan around the pork chops and allow to cook for about 3 additional minutes. The glaze will thicken slightly.
Remove the pork chops from the pan, serve immediately. Pour the glaze over the pork chops when serving (if desired).